WebMar 13, 2024 · For quantitative evaluation, the crosslink density was measured using the Flory–Rehner equation. The crosslink density of the EPDM/silica vulcanizates increased as the silica contents increased. ... Flory, P.J.; Rehner, J. Statistical Mechanics of CrossLinked Polymer Networks, I. Rubber like Elasticity. J. Chem. Phys. 1943, 11, 521. WebFeb 1, 2024 · To date, the only known mathematical models for predicting crosslink density with respect to the properties of constituent polymers are Peppas-Merrill equation Eq. (A.1) in Appendix A (Carr & Peppas, 2009), which is a modification of the Flory-Rehner equation Eq. (A.2) in Appendix A (Bruck, 1961). The models describe the mixing of …

Understanding the effects of cross-linking density on self

WebJan 21, 2024 · Depending on the methodology, the increase in the crosslink density with sulphur content was 1.7 fold for the Flory–Rehner approach and 1.2 fold for both TSSR … WebJan 20, 2024 · The cross-linking density influences the physicochemical properties of cyclodextrin-based nanosponges (CD-NSs). ... exploiting Flory-Rehner theory, and rheology, strongly showed a cross-linker content-dependent behavior. The study of cross-linking density allowed to shed light on the efficiency of the synthesis reaction methods. … dinas island campsite reviews

Revisiting the Flory–Rehner equation: taking a closer look at the Flory …

WebJul 30, 2024 · In this work, the Flory–Rehner equation is revisited to evidence the dependency of the interaction parameter on both polymer volume fraction and temperature. Such an analysis to estimate the true functionality of the interaction parameter is based on experimental data reported in the literature for the swelling behavior of NIPA hydrogels … WebCrosslink density values can be obtained from ν 2 with the Flory-Rehner equation: Χ= − [𝑙𝑛(1−𝜈2)+ 𝜈2+𝜒(𝜈2)2] ((𝜈2) 1 3− 𝜈2 2) where V s is the molar volume of the solvent and χ is the polymer-solvent interaction parameter. The following constant values were used to determine the cross-linking density: d WebCrosslink density also was determined from equilibrium stress- strain measurements. A strip sample with gauge marks was loaded with a small weight, and after 30 minutes, the deformation ... P.J. Flory, J. Rehner, J. Chem. Phys. 1 1, 521 (1943) F.P. Baldwin, G. Ver Strate, Rubber Chem. Technol. 45, 709 (1972) Title ... dina shores children